The Blacklist Season 5 (2013)

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Novice criminal profiler Elizabeth Keen is shocked when her bosses at the FBI give her an urgent summons; criminal mastermind Raymond Reddington has turned himself in, but will only talk to her. Promising to help bring down his former associates if she works with him, Reddington begins naming names from his extensive list of criminal contacts. As Elizabeth works with him on a special FBI task force to bring down terrorists and spies, she begins to realize that her past is inextricably connected with Reddington.